• 1/4 tsp. red pepper flakes
• 1/4 tsp. freshly ground black pepper
To prepare the pork chops: In a large bowl, combine 1 cup warm water, brown sugar and salt. Whisk until sugar and salt are dissolved. Add 3 cups cold water and bourbon. Place pork chops in a 9- by 9-inch baking dish and pour the brine over the chops. They should be submerged. Cover and refrigerate for 1 to 3 hours.
To prepare the glaze: Meanwhile, in a small saucepan, combine ketchup, 3 tablespoons bourbon, molasses, vinegar, Worcestershire sauce, garlic, brown sugar, red pepper and black pepper over medium heat. Bring to a boil. Reduce heat to low and simmer for 10 to 12 minutes, stirring occasionally, until thickened to a glaze consistency.